High surface area and Z′ in a thermally stable 8-fold polycatenated hydrogen-bonded framework

Title:
High surface area and Z′ in a thermally stable 8-fold polycatenated hydrogen-bonded framework
Authors:
Zentner, Cassandra A.; Lai, Holden W. H.; Greenfield, Joshua T.; Wiscons, Ren A.; Zeller, Matthias; Campana, Charles F.; Talu, Orhan; FitzGerald, Stephen; Rowsell, Jesse L. C.
Abstract:
1,3,5-Tris(4-carboxyphenyl) benzene assembles into an intricate 8-fold polycatenated assembly of (6,3) hexagonal nets formed through hydrogen bonds and pi-stacking. One polymorph features 56 independent molecules in the asymmetric unit, the largest Z' reported to date. The framework is permanently porous, with a BET surface area of 1095 m(2) g(-1) and readily adsorbs N-2, H-2 and CO2.
Citation:
Zentner, C.A., H.W.H. Lai, J.T. Greenfield, et al. 2015. "High surface area and Z′ in a thermally stable 8-fold polycatenated hydrogen-bonded framework." Chemical Communications 51(58): 11642-11645.
Publisher:
Royal Society of Chemistry
DATE ISSUED:
2015
Department:
Physics and Astronomy
Type:
Article
PUBLISHED VERSION:
10.1039/C5CC04219D
Additional Links:
http://xlink.rsc.org/?DOI=C5CC04219D
PERMANENT LINK:
http://hdl.handle.net/11282/594357

Full metadata record

DC FieldValue Language
dc.contributor.authorZentner, Cassandra A.en
dc.contributor.authorLai, Holden W. H.en
dc.contributor.authorGreenfield, Joshua T.en
dc.contributor.authorWiscons, Ren A.en
dc.contributor.authorZeller, Matthiasen
dc.contributor.authorCampana, Charles F.en
dc.contributor.authorTalu, Orhanen
dc.contributor.authorFitzGerald, Stephenen
dc.contributor.authorRowsell, Jesse L. C.en
dc.date.accessioned2016-01-19T14:57:44Zen
dc.date.available2016-01-19T14:57:44Zen
dc.date.issued2015en
dc.identifier.citationZentner, C.A., H.W.H. Lai, J.T. Greenfield, et al. 2015. "High surface area and Z′ in a thermally stable 8-fold polycatenated hydrogen-bonded framework." Chemical Communications 51(58): 11642-11645.en
dc.identifier.issn1359-7345en
dc.identifier.urihttp://hdl.handle.net/11282/594357en
dc.description.abstract1,3,5-Tris(4-carboxyphenyl) benzene assembles into an intricate 8-fold polycatenated assembly of (6,3) hexagonal nets formed through hydrogen bonds and pi-stacking. One polymorph features 56 independent molecules in the asymmetric unit, the largest Z' reported to date. The framework is permanently porous, with a BET surface area of 1095 m(2) g(-1) and readily adsorbs N-2, H-2 and CO2.en
dc.language.isoen_USen
dc.publisherRoyal Society of Chemistryen
dc.identifier.doi10.1039/C5CC04219Den
dc.relation.urlhttp://xlink.rsc.org/?DOI=C5CC04219Den
dc.subject.departmentPhysics and Astronomyen_US
dc.titleHigh surface area and Z′ in a thermally stable 8-fold polycatenated hydrogen-bonded frameworken_US
dc.typeArticleen
dc.identifier.journalChemical Communicationsen
dc.subject.keywordMetal-organic frameworksen_US
dc.subject.keywordCrystal structuresen_US
dc.subject.keywordPorous materialsen_US
dc.subject.keywordMoleculesen_US
dc.subject.keywordAciden_US
dc.identifier.volume51en_US
dc.identifier.issue58en_US
dc.rightsArchived with thanks to Chem. Commun.en
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