Vibration Spectra and Assignments of 1,1,2,2-tetrafluoro cyclopropane- d0, d1 and d2

Title:
Vibration Spectra and Assignments of 1,1,2,2-tetrafluoro cyclopropane- d0, d1 and d2
Authors:
Craig, Norman C.; Anderson, Gary J.; Cuellar-Ferreira, Enrique; Koepke, Jeffery W.; Martyn, Peter H.
Abstract:
From i.r. and Raman spectra complete assignments of fundamental vibration frequencies have been obtained for c-C3F4H2, c-C3F4HD and c-C3F4D2. For the undeuterated molecule the assignments are: (a1) 3022, 1526, 1366, 1076, 771, 489 and 291; (a2) [1344], 913, 435 and 194; (b1) 1204,1204, 1026, 828, 618 and 465; (b2) 3115, 1254, 871, [435] and 177 cm−1. The 1344 cm−1 value is tentative, and the 435 cm−1 value is derived from the assignments for the d1 and d2 molecules. A frequency in the 1450–1600 cm−1 region, due principally to ring breathing, has been shown to be a characteristic group frequency for fluorocyclopropanes and related ethylene oxides.
Citation:
Craig, Norman C., Gary J. Anderson, Enrique Cuellar-Ferreira, Jeffery W. Koepke, and Peter H. Martyn. 1972. "Vibration Spectra and Assignments of 1,1,2,2-Tetrafluorocyclopropane-d0,d1 and d2." Spectrochimica Acta Part A: Molecular Spectroscopy 28(6): 1175-1193.
DATE ISSUED:
1972
Department:
Chemistry
Type:
Article
PUBLISHED VERSION:
10.1016/0584-8539(72)80089-8
PERMANENT LINK:
http://hdl.handle.net/11282/334098

Full metadata record

DC FieldValue Language
dc.contributor.authorCraig, Norman C.en
dc.contributor.authorAnderson, Gary J.en
dc.contributor.authorCuellar-Ferreira, Enriqueen
dc.contributor.authorKoepke, Jeffery W.en
dc.contributor.authorMartyn, Peter H.en
dc.date.accessioned2014-11-10T14:13:50Z-
dc.date.available2014-11-10T14:13:50Z-
dc.date.issued1972en
dc.identifier.citationCraig, Norman C., Gary J. Anderson, Enrique Cuellar-Ferreira, Jeffery W. Koepke, and Peter H. Martyn. 1972. "Vibration Spectra and Assignments of 1,1,2,2-Tetrafluorocyclopropane-d0,d1 and d2." Spectrochimica Acta Part A: Molecular Spectroscopy 28(6): 1175-1193.en
dc.identifier.issn0584-8539en
dc.identifier.urihttp://hdl.handle.net/11282/334098-
dc.description.abstractFrom i.r. and Raman spectra complete assignments of fundamental vibration frequencies have been obtained for c-C3F4H2, c-C3F4HD and c-C3F4D2. For the undeuterated molecule the assignments are: (a1) 3022, 1526, 1366, 1076, 771, 489 and 291; (a2) [1344], 913, 435 and 194; (b1) 1204,1204, 1026, 828, 618 and 465; (b2) 3115, 1254, 871, [435] and 177 cm−1. The 1344 cm−1 value is tentative, and the 435 cm−1 value is derived from the assignments for the d1 and d2 molecules. A frequency in the 1450–1600 cm−1 region, due principally to ring breathing, has been shown to be a characteristic group frequency for fluorocyclopropanes and related ethylene oxides.en
dc.language.isoen_USen
dc.identifier.doi10.1016/0584-8539(72)80089-8en
dc.subject.departmentChemistryen
dc.titleVibration Spectra and Assignments of 1,1,2,2-tetrafluoro cyclopropane- d0, d1 and d2en
dc.typeArticleen
dc.identifier.journalSpectrochimica Acta Part A: Molecular Spectroscopyen
dc.identifier.volume28en
dc.identifier.issue6en
dc.identifier.startpage1175en
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