Microwave spectrum, structure, and dipole moment of 3,3‐difluorocyclopropene

Title:
Microwave spectrum, structure, and dipole moment of 3,3‐difluorocyclopropene
Authors:
Ramaprasad, K. R.; Laurie, Victor W.; Craig, Norman C.
Abstract:
The microwave spectra of four isotopic species of 3,3‐difluorocyclopropene have been investigated in the region from 18–40 GHz. Structural parameters obtained are r (C1C2) =1.321±0.001, r (C1C3) =1.438±0.007, r (CH) =1.075±0.001 , r (CF) =1.365±0.005 Å, &FCF=105.5±0.5°, &C1C3C2=54.6±0.4°, &HC1C2=148.4±0.1°. From the Stark effect the dipole moment has been determined to be 2.98±0.02 D.
Citation:
Ramaprasad, K.R., Victor W. Laurie, and Norman C. Craig. 1976. "Microwave spectrum, structure, and dipole moment of 3,3‐difluorocyclopropene." Journal of Chemical Physics 64: 4832-4835.
Publisher:
American Institute of Physics (AIP)
DATE ISSUED:
1976
Department:
Chemistry
Type:
Article
PUBLISHED VERSION:
10.1063/1.432138
PERMANENT LINK:
http://hdl.handle.net/11282/334059

Full metadata record

DC FieldValue Language
dc.contributor.authorRamaprasad, K. R.en
dc.contributor.authorLaurie, Victor W.en
dc.contributor.authorCraig, Norman C.en
dc.date.accessioned2014-11-10T14:13:13Zen
dc.date.available2014-11-10T14:13:13Zen
dc.date.issued1976en
dc.identifier.citationRamaprasad, K.R., Victor W. Laurie, and Norman C. Craig. 1976. "Microwave spectrum, structure, and dipole moment of 3,3‐difluorocyclopropene." Journal of Chemical Physics 64: 4832-4835.en
dc.identifier.issn0021-9606en
dc.identifier.urihttp://hdl.handle.net/11282/334059en
dc.description.abstractThe microwave spectra of four isotopic species of 3,3‐difluorocyclopropene have been investigated in the region from 18–40 GHz. Structural parameters obtained are r (C1C2) =1.321±0.001, r (C1C3) =1.438±0.007, r (CH) =1.075±0.001 , r (CF) =1.365±0.005 Å, &FCF=105.5±0.5°, &C1C3C2=54.6±0.4°, &HC1C2=148.4±0.1°. From the Stark effect the dipole moment has been determined to be 2.98±0.02 D.en
dc.publisherAmerican Institute of Physics (AIP)en
dc.identifier.doi10.1063/1.432138en
dc.subject.departmentChemistryen_US
dc.titleMicrowave spectrum, structure, and dipole moment of 3,3‐difluorocyclopropeneen
dc.typeArticleen
dc.identifier.journalJournal of Chemical Physicsen
dc.subject.keywordElectric dipole momentsen
dc.subject.keywordMicrowave spectraen
dc.subject.keywordStark effecten
dc.identifier.volume64en
dc.identifier.startpage4832en
All Items in The Five Colleges of Ohio Digital Repository are protected by copyright, with all rights reserved, unless otherwise indicated.