Kinetics Study Of The Aromatic Bicyclic Peroxy Radical Plus No Reaction: Overall Rate Constant And Nitrate Product Yield Measurements

Title:
Kinetics Study Of The Aromatic Bicyclic Peroxy Radical Plus No Reaction: Overall Rate Constant And Nitrate Product Yield Measurements
Authors:
Elrod, Matthew J.
Abstract:
The measurements of the overall bicyclic peroxy radical + NO rate constant for the 1,3,5-trimethylbenzene (1,3,5-TMB) system and of the nitrate product yields for the benzene, toluene, p-xylene, and 1,3,5-TMB systems were performed via the turbulent flow chemical ionization mass spectrometry technique. While the overall rate constant was found to be consistent with the value used in the most detailed aromatic oxidation kinetic model (Master Chemical Mechanism, MCM), the nitrate product yields were found to be generally lower than predicted by the MCM and to have a different aromatic species-specific dependence than the MCM predicts.
Citation:
Elrod, Matthew J. 2011. "Kinetics Study Of The Aromatic Bicyclic Peroxy Radical Plus No Reaction: Overall Rate Constant And Nitrate Product Yield Measurements." Journal Of Physical Chemistry A 115(28): 8125-8130.
Publisher:
American Chemical Society
DATE ISSUED:
2011-07
Department:
Chemistry
Type:
article
PUBLISHED VERSION:
10.1021/jp204308f
PERMANENT LINK:
http://hdl.handle.net/11282/310061

Full metadata record

DC FieldValue Language
dc.contributor.authorElrod, Matthew J.en_US
dc.date.accessioned2013-12-23T16:24:23Zen
dc.date.available2013-12-23T16:24:23Zen
dc.date.issued2011-07en
dc.identifier.citationElrod, Matthew J. 2011. "Kinetics Study Of The Aromatic Bicyclic Peroxy Radical Plus No Reaction: Overall Rate Constant And Nitrate Product Yield Measurements." Journal Of Physical Chemistry A 115(28): 8125-8130.en_US
dc.identifier.issn1089-5639en_US
dc.identifier.urihttp://hdl.handle.net/11282/310061en
dc.description.abstractThe measurements of the overall bicyclic peroxy radical + NO rate constant for the 1,3,5-trimethylbenzene (1,3,5-TMB) system and of the nitrate product yields for the benzene, toluene, p-xylene, and 1,3,5-TMB systems were performed via the turbulent flow chemical ionization mass spectrometry technique. While the overall rate constant was found to be consistent with the value used in the most detailed aromatic oxidation kinetic model (Master Chemical Mechanism, MCM), the nitrate product yields were found to be generally lower than predicted by the MCM and to have a different aromatic species-specific dependence than the MCM predicts.en_US
dc.publisherAmerican Chemical Societyen_US
dc.identifier.doi10.1021/jp204308fen
dc.subject.departmentChemistryen_US
dc.titleKinetics Study Of The Aromatic Bicyclic Peroxy Radical Plus No Reaction: Overall Rate Constant And Nitrate Product Yield Measurementsen_US
dc.typearticleen_US
dc.identifier.journalJournal Of Physical Chemistry Aen_US
dc.subject.keywordVolatile organic compoundsen_US
dc.subject.keywordAtmospheric oxidationen_US
dc.subject.keywordTolueneen_US
dc.subject.keywordPhotooxidationen_US
dc.subject.keywordCH3C(O)O-2en_US
dc.identifier.volume115en_US
dc.identifier.issue28en_US
dc.identifier.startpage8125en_US
All Items in The Five Colleges of Ohio Digital Repository are protected by copyright, with all rights reserved, unless otherwise indicated.