Direct kinetics study of the product forming channels of the reaction of isoprene-derived hydroxyperoxy radicals with NO

Title:
Direct kinetics study of the product forming channels of the reaction of isoprene-derived hydroxyperoxy radicals with NO
Authors:
Patchen, Amie K.; Pennino, Michael J.; Kiep, Annastassja C.; Elrod, Matthew J.
Abstract:
A direct kinetics study of the product-forming channels of the reaction of isoprene-derived hydroxyalkylperoxy radicals with NO has been performed at 100 Torr pressure and 298 K using the turbulent flow technique with high-pressure chemical ionization mass spectrometry for the detection of reactants and products. For comparative purposes, a similar study was also performed for the reaction of 1- and 2-butene-derived hydroxyalkylperoxy radicals with NO. The measured hydroxyalkylnitrate product channel branching ratios were determined to be 0.061, 0.068, and 0.070 for the 1-butene, 2-butene, and isoprene systems, respectively. The results are compared to previous measurements of the hydroxyalkylnitrate-branching ratios for these systems, and the atmospheric significance of the results is discussed.
Citation:
Patchen, A.K., M.J. Pennino, A.C. Kiep, AND M.J. Elrod. 2007. "Direct Kinetics Study of the Product Forming Channels of the Reaction of Isoprene-Derived Hydroxyperoxy Radicals with NO." International Journal of Chemical Kinetics 39(6): 353-361.
Publisher:
Wiley-Blackwell
DATE ISSUED:
2007-06
Department:
Chemistry
Type:
article
PUBLISHED VERSION:
10.1002/kin.20248
PERMANENT LINK:
http://hdl.handle.net/11282/309729

Full metadata record

DC FieldValue Language
dc.contributor.authorPatchen, Amie K.en_US
dc.contributor.authorPennino, Michael J.en_US
dc.contributor.authorKiep, Annastassja C.en_US
dc.contributor.authorElrod, Matthew J.en_US
dc.date.accessioned2013-12-23T16:16:28Zen
dc.date.available2013-12-23T16:16:28Zen
dc.date.issued2007-06en
dc.identifier.citationPatchen, A.K., M.J. Pennino, A.C. Kiep, AND M.J. Elrod. 2007. "Direct Kinetics Study of the Product Forming Channels of the Reaction of Isoprene-Derived Hydroxyperoxy Radicals with NO." International Journal of Chemical Kinetics 39(6): 353-361.en_US
dc.identifier.issn0538-8066en_US
dc.identifier.urihttp://hdl.handle.net/11282/309729en
dc.description.abstractA direct kinetics study of the product-forming channels of the reaction of isoprene-derived hydroxyalkylperoxy radicals with NO has been performed at 100 Torr pressure and 298 K using the turbulent flow technique with high-pressure chemical ionization mass spectrometry for the detection of reactants and products. For comparative purposes, a similar study was also performed for the reaction of 1- and 2-butene-derived hydroxyalkylperoxy radicals with NO. The measured hydroxyalkylnitrate product channel branching ratios were determined to be 0.061, 0.068, and 0.070 for the 1-butene, 2-butene, and isoprene systems, respectively. The results are compared to previous measurements of the hydroxyalkylnitrate-branching ratios for these systems, and the atmospheric significance of the results is discussed.en_US
dc.language.isoen_USen_US
dc.publisherWiley-Blackwellen_US
dc.identifier.doi10.1002/kin.20248en
dc.subject.departmentChemistryen_US
dc.titleDirect kinetics study of the product forming channels of the reaction of isoprene-derived hydroxyperoxy radicals with NOen_US
dc.typearticleen_US
dc.identifier.journalInternational Journal of Chemical Kineticsen_US
dc.subject.keywordNitratesen_US
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